edit: this post is a bit of a rant on tone stacks, sorry. its also largely my opinion, not fact, you can probably skip the whole post and not miss anything of value. proceed with caution
on distortions i personally prefer the baxandall over the classic 3-band styles of tone controls, since it feels like i have better mid range control with a baxandall (or James for that matter). (despite those tone stacks not having a mid control, you can actually boost the mids, instead of only scooping.)
peaking and scooping controls with narrower bandwidth feel less natural, more polished, which is fine for some applications (modern metal/rock), but not for others (punk/blues)
less is more, especially with knobs, a 2 or 3 knob OD/DST/FZ is often way easier to get a satisfying tone out of than a 4 or more knob pedal. probably has to do with choice paralysis.
another good tone control is the BMP in the feedback loop of an opamp.
this basically makes it a boosting tone control. when its in the middle, the original mid scoop transforms in a mid boost, and turning it either boosts more bass or more trebble. it needs an extra 5k6 resistor on the former bass side (which is now the treble) to not oscillate on the brightest setting, but its really easy to use and sounds amazing. (a call this the inverted Big Muff Pi tonestack, since the frequency transfer graph is flipped upside down)
i'd also like to confess that, despite my experimentation with lots of tone controls, i generally leave out any types of tone control on my pedals, or gain control for that matter. i love the infiltered, broken but open sounds that come from un-filtered clipping!
IMHO, the best guitar sounds are from little tiny practice amps with all knobs on 10, distorting their little transistor 'power' amps to heck and back. this is always unfiltered, raw and pure.
my opinion in conclusion:
none > bax/james > inv. BMP > norm. BMP > 3-band > simple treble roll-off
cheers, Iain