Thanks very much Ben, that string-to-wire colour info is good to have! I'm not sure if the magnetic pickup versus piezo will be a big issue though, as long as there is a separate signal for each string. The biggest problem, I think, is figuring out what kind of signal the controller wants to see, and how to achieve this signal.
EDIT:
I just opened up the Gvox processor box, and had a good look around (sorry, I don't have a camera, otherwise I'd put up some pics). Inside, there's one PCB, and components are surface mount. As you will no doubt be able to tell, this stuff isn't exactly my speciality, but anyway...
The first half of the board looks to be an analog input section. The six signals from the pickup travel through a fairly extensive resistor-capacitor network, along with one trim pot per string (signal strength adjustment), and one 14 pin IC per string. The ICs are called P7F4, which according to online data sheets is a single-phase, full-wave, bridge rectifier. I guess all this is flatten the six individual signals and 'prepare' them for the digital section (?).
The second half of the board looks like microcontroller set-up (has CPU/memory/clock crystal/etc.). The two 'main' ICs are unidentifiable: the smaller one (32 pin) has a sticker over it, and the larger one (68 pin) has been sanded (

!) on top to remove the print. I'm assuming these are the brains/processor of the unit.
Additionally, the digital portion of the PCB contains the following ICs (descriptions are from data sheets I found online):
HC373 (20 pin): 3-state, octal, D-type latch
CXK58257AM-10L (28 pin): 32768-word X 8-bit, high-speed, CMOS static RAM
HC04 (14 pin): Hex inverter (contains six independent inverters).
What's also interesting is that it looks like provisions have been made for a battery to be attached to the PCB, however, this provision hasn't been implemented.
In terms of output, there are only three wires (brown, black, red) going to the output serial plug (9-pin, "D" shape), designed to be hooked up to a PC.
Black is connected to digital ground.
Brown is connected to pin 10 of the HC04 chip.
Red is connected to pin 9 of the HC04 chip.
As mentioned above, the HC04 is a "hex inverter" chip, containing six independent inverters. From the data sheet, it would seem that pin 9 is the inverter number 4 input, and pin 10 is the inverter number 5 output. Considering the serial plug is meant to connect to a PC, I'm guessing the red wire is therefore for the PC to send information to the Gvox, and the brown wire for the Gvox to send information to the PC.
(HC04 data sheet:
http://rocky.digikey.com/WebLib/Texas%20Instruments/Web%20data/SN74HC04.pdf)
Given this, and the here-say info from my first post -that the hex signal was multiplexed to the ring of a stereo quarter inch jack- would it be safe to assume that I should try wiring the brown wire to the ring, and the black wire to the sleeve? The controller rack has a plain audio out at the back too; I'm wondering if an analog signal from the hex may have been fed to the tip of the input plug. But in that case, what should be used for the ground signal (sleeve), analog or digital ground?